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Fundamental Insights into the Covalent Silane Functionalization of NiFe Layered Double Hydroxides
Author(s) -
Carrasco Jose A.,
SeijasDa Silva Alvaro,
Oestreicher Víctor,
Romero Jorge,
Márkus Bence G.,
Simon Ferenc,
Vieira Bruno J. C.,
Waerenborgh João C.,
Abellán Gonzalo,
Coronado Eugenio
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201905397
Subject(s) - surface modification , triethoxysilane , layered double hydroxides , silanes , silane , covalent bond , thermogravimetric analysis , materials science , molecule , hybrid material , chemical engineering , inorganic chemistry , chemistry , ion exchange , nanotechnology , organic chemistry , ion , hydroxide , engineering
Layered double hydroxides (LDHs) are a class of 2D anionic materials exhibiting wide chemical versatility and promising applications in different fields, ranging from catalysis to energy storage and conversion. However, the covalent chemistry of this kind of 2D materials is still barely explored. Herein, the covalent functionalization with silanes of a magnetic NiFe‐LDH is reported. The synthetic route consists of a topochemical approach followed by anion exchange reaction with surfactant molecules prior to covalent functionalization with the (3‐aminopropyl)triethoxysilane (APTES) molecules. The functionalized NiFe‐APTES was fully characterized by X‐ray diffraction, infrared spectroscopy, electron microscopy, thermogravimetric analysis coupled with mass spectrometry and 29 Si solid‐state nuclear magnetic resonance, among others. The effect on the electronic properties of the functionalized LDH was investigated by a magnetic study in combination with Mössbauer spectroscopy. Moreover, the reversibility of the silane‐functionalization at basic pH was demonstrated, and the quality of the resulting LDH was proven by studying the electrochemical performance in the oxygen evolution reaction in basic media. Furthermore, the anion exchange capability for the NiFe‐APTES was tested employing Cr VI , resulting in an increase of 200 % of the anion retention. This report allows for a new degree of tunability of LDHs, opening the door to the synthesis of new hybrid architectures and materials.