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Amino‐Induced 2D Cu‐Based Metal–Organic Framework as an Efficient Heterogeneous Catalyst for Aerobic Oxidation of Olefins
Author(s) -
Tang Jia,
Cai Mengke,
Xie Guanqun,
Bao Shixiong,
Ding Shujiang,
Wang Xiaoxia,
Tao Jinzhang,
Li Guangqin
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201905249
Subject(s) - vicinal , catalysis , metalation , chemistry , metal organic framework , hydrogen bond , heterogeneous catalysis , ligand (biochemistry) , reactivity (psychology) , copper , hydrogen , metal , combinatorial chemistry , molecule , organic chemistry , adsorption , pathology , medicine , biochemistry , receptor , alternative medicine
Abstract With the assistance of hydrogen bonds of the o ‐amino group, we have successfully tuned a coordination structure from a metal–organic polyhedron (MOP) to a two‐dimensional (2D) metal–organic framework (MOF). The amino group forms hydrogen bonds with the two vicinal carboxylic groups, and induces the ligand to coordinate with copper ions to form the 2D structure. The obtained 2D Cu‐based MOF (Cu‐AIA) has been applied as an efficient heterogeneous catalyst in the aerobic epoxidation of olefins by using air as oxygen source. Without the aggregation problem of active sites in MOPs, Cu‐AIA possesses much higher reactivity than MOP‐1. Furthermore, the amino group of the framework has been used as a modifiable site through post‐synthetic metalation (PSMet) to prepare a 2D MOF‐supported Pd single‐site heterogeneous catalyst, which shows excellent catalytic performance for the Suzuki reaction. It indicates that Cu‐AIA can also work as a good 2D MOF carrier for the derivation of other heterogeneous catalysts.