Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P) 2 M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb) | Zendy

Balmer Markus | Zendy; Franzke Yannick J. | Zendy; Weigend Florian | Zendy; Hänisch Carsten | Zendy

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Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P) 2 M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)

Author(s) -

Balmer Markus,

Franzke Yannick J.,

Weigend Florian,

Hänisch Carsten

Publication year - 2020

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201905061

Subject(s) - group (periodic table) , crystallography , quantum chemical , chemistry , stereochemistry , molecule , organic chemistry

Herein, the synthesis of new low‐valent Group 14 phosphinidenide complexes [({SIDipp}P) 2 M ] exhibiting P–M pπ–pπ interactions (SIDipp=1,3‐bis(2,6‐diisopropylphenyl)‐imidazolidin‐2‐ylidene, M=Ge, Sn, Pb), is presented. These compounds were investigated by means of structural, spectroscopic, and quantum‐chemical methods. Furthermore, the monosubstituted compounds [(SIDippP)MX] 2 (M=Sn, X=Cl; M=Pb, X=Br) are presented, which show dimeric structures instead of multiple bonding interaction.

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