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Cover Feature: Cubane Electrochemistry: Direct Conversion of Cubane Carboxylic Acids to Alkoxy Cubanes Using the Hofer–Moest Reaction under Flow Conditions (Chem. Eur. J. 2/2020)
Author(s) -
Collin Diego E.,
FolgueirasAmador Ana A.,
Pletcher Derek,
Light Mark E.,
Linclau Bruno,
Brown Richard C. D.
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201905028
Subject(s) - cubane , electrochemistry , chemistry , ammonite , cover (algebra) , geology , organic chemistry , paleontology , electrode , molecule , engineering , cretaceous , mechanical engineering
Cubane has been known about for more than half a century, but methods for direct functionalization of commercial cubane derivatives remain somewhat limited. The possibility of using electrochemical methods to transform cubane carboxylic acids presented an intriguing possibility, leading to the development of anodic decarboxylative ether formation in flow. The image, created by Noémie Collin, shows an ammonite fossil merged with an “Ammonite” flow electrolysis cell; electricity drives oxidation of the carboxylate functionality to form cubyl ethers. More information can be found in the Communication by B. Linclau, R. C. D. Brown, et al. on page 374.