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Cover Feature: Syntheses and Characterization of a Pair of Isomers of Heteroleptic Bis(Bidentate) Ruthenium(II) Complexes with Two Different Monodentate Ligands (Chem. Eur. J. 72/2019)
Author(s) -
Toyama Mari,
Takizawa Takako,
Morita Itaru,
Nagao Noriharu,
Kuramochi Yusuke,
Ishida Hitoshi
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201904912
Subject(s) - denticity , ruthenium , chemistry , stereochemistry , bipyridine , crystallography , medicinal chemistry , crystal structure , catalysis , organic chemistry
A pair of isomers of heteroleptic bis(bidentate) ruthenium(II) complexes with two different monodentate ligands, cis ‐[Ru(L)(L’)XY] n + (L≠L’: bidentate ligands; X≠Y: monodentate ligands), has been synthesized for the first time. trans (Cl,N bpy )‐[Ru(bpy)Cl(dmso‐ S )(Hdpa)] + (bpy: 2,2’‐bipyridine; Hdpa: di‐2‐pyridylamine) has a deep red color while the trans (Cl,N Hdpa )‐isomer is yellow; these together with the DFT calculations and the CV studies are discussed. More information can be found in the Full Paper by M. Toyama, N. Nagao, H. Ishida et al. on page 16582.