Structural Diversity of F‐Element Monophthalocyanine Complexes | Zendy

Zhou Wen | Zendy; McKearney Declan | Zendy; Leznoff Daniel B. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Structural Diversity of F‐Element Monophthalocyanine Complexes

Author(s) -

Zhou Wen,

McKearney Declan,

Leznoff Daniel B.

Publication year - 2020

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201904535

Subject(s) - halide , lanthanide , actinide , phthalocyanine , chemistry , reactivity (psychology) , uranium , characterization (materials science) , hydrolysis , ring (chemistry) , metal , cluster (spacecraft) , crystallography , uranyl , stereochemistry , inorganic chemistry , materials science , organic chemistry , nanotechnology , ion , metallurgy , medicine , alternative medicine , pathology , computer science , programming language

The preparation and structural characterization of a series of lanthanide and uranium(IV) phthalocyanine halide complexes were achieved by reaction of the corresponding metal halide with Li 2 Pc. A preliminary survey of their reactivity includes ring reduction of Li(THF) 4 [PcUCl 3 ] with KC 8 leading to the first structurally characterized Pc 4− actinide complex, hydrolysis of PcDyCl(DMSO) to PcDyOH(H 2 O) 3 and preparation of a unique trimeric triangular Li(PcDy) 3 (OH) 4 (H 2 O) cluster.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research