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Structural Diversity of F‐Element Monophthalocyanine Complexes
Author(s) -
Zhou Wen,
McKearney Declan,
Leznoff Daniel B.
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201904535
Subject(s) - halide , lanthanide , actinide , phthalocyanine , chemistry , reactivity (psychology) , uranium , characterization (materials science) , hydrolysis , ring (chemistry) , metal , cluster (spacecraft) , crystallography , uranyl , stereochemistry , inorganic chemistry , materials science , organic chemistry , nanotechnology , ion , metallurgy , medicine , alternative medicine , pathology , computer science , programming language
The preparation and structural characterization of a series of lanthanide and uranium(IV) phthalocyanine halide complexes were achieved by reaction of the corresponding metal halide with Li 2 Pc. A preliminary survey of their reactivity includes ring reduction of Li(THF) 4 [PcUCl 3 ] with KC 8 leading to the first structurally characterized Pc 4− actinide complex, hydrolysis of PcDyCl(DMSO) to PcDyOH(H 2 O) 3 and preparation of a unique trimeric triangular Li(PcDy) 3 (OH) 4 (H 2 O) cluster.