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Micro/Nanoengineered α‐Fe 2 O 3 Nanoaggregate Conformably Enclosed by Ultrathin N‐Doped Carbon Shell for Ultrastable Lithium Storage and Insight into Phase Evolution Mechanism
Author(s) -
Xie Dan,
Li HuanHuan,
Shi YanHong,
Diao WanYue,
Jiang Ru,
Sun HaiZhu,
Wu XingLong,
Li Wenliang,
Fan ChaoYing,
Zhang JingPing
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201903893
Subject(s) - anode , materials science , electrolyte , electrode , electrochemistry , lithium (medication) , high resolution transmission electron microscopy , chemical engineering , nanoparticle , nanotechnology , analytical chemistry (journal) , transmission electron microscopy , chemistry , chromatography , engineering , endocrinology , medicine
The Fe‐based transition metal oxides are promising anode candidates for lithium storage considering their high specific capacity, low cost, and environmental compatibility. However, the poor electron/ion conductivity and significant volume stress limit their cycle and rate performances. Furthermore, the phenomena of capacity rise and sudden decay for α‐Fe 2 O 3 have appeared in most reports. Here, a uniform micro/nano α‐Fe 2 O 3 nanoaggregate conformably enclosed in an ultrathin N‐doped carbon network (denoted as M/N‐α‐Fe 2 O 3 @NC) is designed. The M/N porous balls combine the merits of secondary nanoparticles to shorten the Li + transportation pathways as well as alleviating volume expansion, and primary microballs to stabilize the electrode/electrolyte interface. Furthermore, the ultrathin carbon shell favors fast electron transfer and protects the electrode from electrolyte corrosion. Therefore, the M/N‐α‐Fe 2 O 3 @NC electrode delivers an excellent reversible capacity of 901 mA h g −1 with capacity retention up to 94.0 % after 200 cycles at 0.2 A g −1 . Notably, the capacity rise does not happen during cycling. Moreover, the lithium storage mechanism is elucidated by ex situ XRD and HRTEM experiments. It is verified that the reversible phase transformation of α↔γ occurs during the first cycle, whereas only the α‐Fe 2 O 3 phase is reversibly transformed during subsequent cycles. This study offers a simple and scalable strategy for the practical application of high‐performance Fe 2 O 3 electrodes.