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Cover Feature: Phosphorus Post‐Functionalization of Diphosphahexaarenes (Chem. Eur. J. 57/2019)
Author(s) -
Hindenberg Philip,
Rominger Frank,
RomeroNieto Carlos
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201903781
Subject(s) - phosphorus , cover (algebra) , surface modification , chemistry , combinatorial chemistry , feature (linguistics) , organic chemistry , engineering , mechanical engineering , linguistics , philosophy
Diphosphahexaarenes , large linearly fused systems containing two six‐membered phosphorus heterocycles, can be readily post‐functionalized at the phosphorus atoms. Thus, the same scaffold can lead to derivatives with different electronic and optical properties without compromising the stability of the system. In addition, complexation of B(C 6 F 5 ) 3 to the oxidized phosphorus atoms further allows control of the properties of the diphosphahexaarenes. More information can be found in the Full Paper by C. Romero‐Nieto et al. on page 13146.