Premium
Oxo‐Thiolation of Cationically Polymerizable Alkenes Using Flow Microreactors
Author(s) -
Ashikari Yosuke,
Saito Kodai,
Nokami Toshiki,
Yoshida Junichi,
Nagaki Aiichiro
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201903426
Subject(s) - cationic polymerization , microreactor , chemoselectivity , chemistry , polymerization , flow chemistry , flow (mathematics) , anodic oxidation , chemical engineering , organic chemistry , polymer chemistry , catalysis , photochemistry , combinatorial chemistry , anode , polymer , geometry , mathematics , electrode , engineering
The present study describes the cationic oxo‐thiolation of polymerizable alkenes by using highly reactive cationic species generated by anodic oxidation. These highly reactive cations were able to activate alkenes before their polymerization. Fast mixing in flow microreactors effectively controlled chemoselectivity, enabling higher reaction temperatures.