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Cover Feature: Photoluminescent Lanthanide(III) Single‐Molecule Magnets in Three‐Dimensional Polycyanidocuprate(I)‐Based Frameworks (Chem. Eur. J. 51/2019)
Author(s) -
Zakrzewski Jakub J.,
Chorazy Szymon,
Nakabayashi Koji,
Ohkoshi Shinichi,
Sieklucka Barbara
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201903216
Subject(s) - lanthanide , photoluminescence , magnet , cover (algebra) , single molecule magnet , metal organic framework , luminescence , relaxation (psychology) , materials science , molecule , feature (linguistics) , copper , magnetization , nanotechnology , chemistry , optoelectronics , physics , magnetic field , organic chemistry , mechanical engineering , quantum mechanics , ion , linguistics , philosophy , engineering , metallurgy , social psychology , psychology , adsorption
Quantum magnets in 3D frameworks : Unprecedented three‐dimensional cyanido‐bridged networks based on lanthanide(III) and copper(I) centers were synthesized. They exhibit tunable visible‐to‐NIR photoluminescence and slow relaxation of the magnetization effect related to the incorporated 4f metal complexes. The 3D network serves as an efficient coordination scaffold to achieve luminescent single‐molecule magnets. More information can be found in the Communication by S. Chorazy et al. on page 11820.