Premium
Cover Feature: Dynamic Studies on Kinetic H 2 /D 2 Quantum Sieving in a Narrow Pore Metal–Organic Framework Grown on a Sensor Chip (Chem. Eur. J. 46/2019)
Author(s) -
Paschke Benjamin,
Denysenko Dmytro,
Bredenkötter Björn,
Sastre German,
Wixforth Achim,
Volkmer Dirk
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201902799
Subject(s) - metal organic framework , cover (algebra) , kinetic energy , diffusion , quantum , dynamic range , materials science , metal , analytical chemistry (journal) , chemistry , physics , thermodynamics , optics , organic chemistry , mechanical engineering , adsorption , quantum mechanics , engineering
A metal–organic framework (MFU‐4) with ultra‐narrow pores has been integrated on a specially designed sensor, with response in the range of milliseconds, and based on surface acoustic waves (SAWs). Selective diffusion of D 2 in H 2 /D 2 mixtures below 64 K has been observed due to kinetic quantum‐sieving. More information can be found in the Communication by G. Sastre, A. Wixforth, D. Volkmer, et al. on page 10803.