Mild and Practical Dirhodium(II)/NHPI‐Mediated Allylic and Benzylic Oxidations with Air as the Oxidant | Zendy

Wang Yi | Zendy; Chen Xiaochuan | Zendy; Jin Hong | Zendy; Wang Yuanhua | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Mild and Practical Dirhodium(II)/NHPI‐Mediated Allylic and Benzylic Oxidations with Air as the Oxidant

Author(s) -

Wang Yi,

Chen Xiaochuan,

Jin Hong,

Wang Yuanhua

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201902739

Subject(s) - allylic rearrangement , dissociation (chemistry) , chemistry , catalysis , axial symmetry , medicinal chemistry , bond dissociation energy , open air , photochemistry , organic chemistry , physics , engineering , architectural engineering , quantum mechanics

Abstract Aerobic allylic and benzylic oxidations catalyzed by dirhodium(II) complexes with N ‐hydroxyphthalimide (NHPI) are described. The open flask reaction occurs at mild temperature, using air as the oxidant. Mechanistic studies suggest that dirhodium(II) complexes axially coordinate with NHPI to activate the O−H bond in NHPI and decrease the bond‐dissociation energy (BDE).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research