Premium
Through‐Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: Ag II ⋅⋅⋅Ag II , Ag II ⋅⋅⋅Ag III , and Ag III ⋅⋅⋅Ag III Metallophilic Interactions
Author(s) -
Singh Akhil Kumar,
Usman Mohammad,
Sciortino Giuseppe,
Garribba Eugenio,
Rath Sankar Prasad
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201902705
Subject(s) - porphyrin , dimer , crystallography , chemistry , photochemistry , organic chemistry
Invited for the cover of this issue are Sankar Prasad Rath and co‐workers at the Indian Institute of Technology (IIT Kanpur) and the University of Sassari. The image depicts through space interactions in a cofacial Ag II porphyrin dimer upon stepwise oxidations, which allow the estimation of the structure and energy characteristics of metallophilic interactions between Ag II /Ag II (d 9 /d 9 ), Ag III /Ag III (d 8 /d 8 ) and also mixed‐valent Ag II /Ag III (d 9 /d 8 ) complexes. Read the full text of the article at 10.1002/chem.201901731.