Front Cover: Through‐Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: Ag II ⋅⋅⋅Ag II , Ag II ⋅⋅⋅Ag III , and Ag III ⋅⋅⋅Ag III  Metallophilic Interactions (Chem. Eur. J. 43/2019) | Zendy

Singh Akhil Kumar | Zendy; Usman Mohammad | Zendy; Sciortino Giuseppe | Zendy; Garribba Eugenio | Zendy; Rath Sankar Prasad | Zendy

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Front Cover: Through‐Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: Ag II ⋅⋅⋅Ag II , Ag II ⋅⋅⋅Ag III , and Ag III ⋅⋅⋅Ag III Metallophilic Interactions (Chem. Eur. J. 43/2019)

Author(s) -

Singh Akhil Kumar,

Usman Mohammad,

Sciortino Giuseppe,

Garribba Eugenio,

Rath Sankar Prasad

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201902704

Subject(s) - porphyrin , dimer , chemistry , front cover , space (punctuation) , crystallography , cover (algebra) , inorganic chemistry , photochemistry , organic chemistry , mechanical engineering , linguistics , philosophy , engineering

Metallophilic interactions have become a popular tool for a variety of high‐end materials‐related applications. Such interactions were investigated by stepwise oxidations using a cis ethene‐bridged silver(II) porphyrin dimer. Besides silver(II)⋅⋅⋅silver(II) (d 9 /d 9 ) interactions, stepwise oxidations also enabled the achievement of various hitherto unknown silver(II)⋅⋅⋅silver(III) (d 9 /d 8 ) and Ag III ⋅⋅⋅Ag III (d 8 /d 8 ) interactions, which allow significant modulation of structure and properties. More information can be found in the Full Paper by S. P. Rath et al. on page 10098.

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