β‐CsB 9 O 14 : A Triple‐Layered Borate with Edge‐Sharing BO 4  Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence | Zendy

Han Shujuan | Zendy; Huang Chunmei | Zendy; Tudi Abudukadi | Zendy; Hu Shuaishuai | Zendy; Yang Zhihua | Zendy; Pan Shilie | Zendy

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β‐CsB 9 O 14 : A Triple‐Layered Borate with Edge‐Sharing BO 4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

Author(s) -

Han Shujuan,

Huang Chunmei,

Tudi Abudukadi,

Hu Shuaishuai,

Yang Zhihua,

Pan Shilie

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201902527

Subject(s) - birefringence , tetrahedron , boron , materials science , enhanced data rates for gsm evolution , cutoff , crystallography , crystal structure , optics , chemistry , physics , telecommunications , organic chemistry , quantum mechanics , computer science

The first triple‐layered borate with edge‐sharing BO 4 tetrahedra, β‐CsB 9 O 14 was obtained under vacuum‐sealed condition. It represents a new structure type and enriches the structural diversity of borates. Moreover, β‐CsB 9 O 14 exhibits a short UV cutoff edge and a large birefringence, indicating that it could be regarded as a DUV birefringent crystal.

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