Reversible Activation of Water by an Air‐ and Moisture‐Stable Frustrated Rhodium Nitrogen Lewis Pair | Zendy

Carmona María | Zendy; Ferrer Joaquina | Zendy; Rodríguez Ricardo | Zendy; Passarelli Vincenzo | Zendy; Lahoz Fernando J. | Zendy; GarcíaOrduña Pilar | Zendy; CañadillasDelgado Laura | Zendy; Carmona Daniel | Zendy

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Reversible Activation of Water by an Air‐ and Moisture‐Stable Frustrated Rhodium Nitrogen Lewis Pair

Author(s) -

Carmona María,

Ferrer Joaquina,

Rodríguez Ricardo,

Passarelli Vincenzo,

Lahoz Fernando J.,

GarcíaOrduña Pilar,

CañadillasDelgado Laura,

Carmona Daniel

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201902452

Subject(s) - rhodium , frustrated lewis pair , nitrogen , chemistry , ligand (biochemistry) , guanidine , medicinal chemistry , moisture , ring (chemistry) , crystallography , stereochemistry , polymer chemistry , lewis acids and bases , catalysis , organic chemistry , receptor , biochemistry

[Cp*Rh(κ 3 N , N ′, P ‐ L )][SbF 6 ] (Cp*=C 5 Me 5 ), bearing a guanidine‐derived phosphano ligand L , behaves as a “dormant” frustrated Lewis pair and activates H 2 and H 2 O in a reversible manner. When D 2 O is employed, a facile H/D exchange at the Cp* ring takes place through sequential C(sp 3 )−H bond activation.

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