Highly Proton‐Conductive Zinc Metal‐Organic Framework Based On Nickel(II) Porphyrinylphosphonate | Zendy

Enakieva Yulia Y. | Zendy; Sinelshchikova Anna A. | Zendy; Grigoriev Mikhail S. | Zendy; Chernyshev Vladimir V. | Zendy; Kovalenko Konstantin A. | Zendy; Stenina Irina A. | Zendy; Yaroslavtsev Andrey B. | Zendy; Gorbunova Yulia G. | Zendy; Tsivadze Aslan Y. | Zendy

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Highly Proton‐Conductive Zinc Metal‐Organic Framework Based On Nickel(II) Porphyrinylphosphonate

Author(s) -

Enakieva Yulia Y.,

Sinelshchikova Anna A.,

Grigoriev Mikhail S.,

Chernyshev Vladimir V.,

Kovalenko Konstantin A.,

Stenina Irina A.,

Yaroslavtsev Andrey B.,

Gorbunova Yulia G.,

Tsivadze Aslan Y.

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201902212

Subject(s) - nickel , proton , conductivity , zinc , metal , inorganic chemistry , solid state , materials science , electrical conductor , chemistry , organic chemistry , physics , composite material , quantum mechanics

The design of new solid‐state proton‐conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate‐based MOF ( IPCE‐1Ni ), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE‐1Ni exhibits one of the highest value of the proton conductivity among reported proton‐conducting MOF materials based on porphyrins (1.55×10 −3 S cm −1 at 75 °C and 80 % relative humidity).

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