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Highly Proton‐Conductive Zinc Metal‐Organic Framework Based On Nickel(II) Porphyrinylphosphonate
Author(s) -
Enakieva Yulia Y.,
Sinelshchikova Anna A.,
Grigoriev Mikhail S.,
Chernyshev Vladimir V.,
Kovalenko Konstantin A.,
Stenina Irina A.,
Yaroslavtsev Andrey B.,
Gorbunova Yulia G.,
Tsivadze Aslan Y.
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201902212
Subject(s) - nickel , proton , conductivity , zinc , metal , inorganic chemistry , solid state , materials science , electrical conductor , chemistry , organic chemistry , physics , composite material , quantum mechanics
The design of new solid‐state proton‐conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate‐based MOF ( IPCE‐1Ni ), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE‐1Ni exhibits one of the highest value of the proton conductivity among reported proton‐conducting MOF materials based on porphyrins (1.55×10 −3 S cm −1 at 75 °C and 80 % relative humidity).