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Cover Feature: Alloyed Tetranuclear Metal Chains of Pd 4− n Pt n ( n= 0–3) Scaffolded by a New Linear Tetraphosphine Containing a PNP Bridge (Chem. Eur. J. 35/2019)
Author(s) -
Tanase Tomoaki,
Tanaka Miho,
Hamada Mami,
Morita Yuka,
Nakamae Kanako,
Ura Yasuyuki,
Nakajima Takayuki
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201901873
Subject(s) - metal , chain (unit) , chemistry , cover (algebra) , crystallography , materials science , stereochemistry , physics , organic chemistry , engineering , mechanical engineering , astronomy
Alloyed metal chains : A new linearly ordered tetraphosphine containing a PN(Ph)P phosphazane bridge, rac ‐bis[(diphenylphosphinomethyl)phenylphosphino]phenylamine ( rac ‐dpmppan), was synthesized and utilized to scaffold a series of Pd 4− n Pt n mixed‐metal linear complexes [Pd 4− n Pt n ( μ ‐ rac ‐dpmppan) 2 (XylNC) 2 ](PF 6 ) 2 ( n =1—3), including Pd 4 , PtPd 3 , PtPd 2 Pt, Pt 2 Pd 2 , and Pt 2 PdPt chains, which are recognized as unprecedented alloyed metal atom chains. More information can be found in the Communication by T. Tanase, T. Nakajima et al. on page 8219.