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Support‐Free Pd 3 Co NCs as an Efficient Heterogeneous Nanocatalyst for New Organic Transformations of C−C Coupling Reactions
Author(s) -
Pradhan Samjhana,
Mishra Kanchan,
Lee Yong Rok
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201901834
Subject(s) - bimetallic strip , palladium , catalysis , cobalt , sonogashira coupling , x ray photoelectron spectroscopy , coupling reaction , materials science , suzuki reaction , heterogeneous catalysis , hydrothermal reaction , chemistry , hydrothermal circulation , chemical engineering , inorganic chemistry , organic chemistry , engineering
A support‐free heterogeneous Pd 3 Co nanostructured composite (NC), synthesized through a hydrothermal route, acted as an effective catalytic system in multivariate Heck‐, Sonogashira‐, and Suzuki‐type coupling reactions of iodonium ylides. The XPS analysis of the bimetallic Pd 3 Co NCs confirmed the elemental composition as 75 % palladium and 25 % cobalt. Furthermore, high‐resolution (HR) TEM analysis confirmed the spherical morphology of the Pd 3 Co bimetallic nanoparticles. The average diameter of the NCs is 14.8 nm. The coupling reaction proceeded through the generation of α‐iodoenones with simultaneous migration of the phenyl group, thereby giving a scaffold with higher atom economy. The heterogeneous Pd 3 Co NCs were recycled and reused without any significant change in catalytic ability for up to five reaction cycles. The high concentration of Pd and association of cobalt into the lattice of palladium appears to enhance its catalytic ability for the diverse coupling reactions in comparison with its monometallic counterparts as well as with bimetallic NCs with a comparatively lesser amount of Pd.