Premium
Solvoluminescence of Cerium(III) Thiocyanate Complex
Author(s) -
Kuramochi Yusuke,
Sayama Shunsuke,
Satake Akiharu
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201901528
Subject(s) - acetonitrile , cerium , thiocyanate , quantum yield , chemistry , inorganic chemistry , yield (engineering) , photochemistry , nitrogen , nuclear chemistry , organic chemistry , materials science , fluorescence , physics , quantum mechanics , metallurgy
A cerium(III) thiocyanate complex shows bright‐blue emission at approximately 450 nm in acetonitrile, the quantum yield of which reaches more than 40 % at 298 K. Non‐coordinating solvents such as acetonitrile give blue emission whereas oxygen‐coordinating and nitrogen‐coordinating solvents afford near UV and green emissions, respectively.