Cyclization of Terphenyl‐Bisfluorenols: A Mechanistic Study of the Regioselectvity | Zendy

Poriel Cyril | Zendy; Barrière Frédéric | Zendy; RaultBerthelot Joëlle | Zendy; Thirion Damien | Zendy

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Cyclization of Terphenyl‐Bisfluorenols: A Mechanistic Study of the Regioselectvity

Author(s) -

Poriel Cyril,

Barrière Frédéric,

RaultBerthelot Joëlle,

Thirion Damien

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201901457

Subject(s) - fluorene , terphenyl , regioselectivity , chemistry , stereochemistry , organic chemistry , catalysis , polymer

The mechanism of the bicyclization reaction of a series of terphenyl‐bisfluorenols into dispiro[fluorene‐9,6′‐indeno[1,2‐ b ]fluorene‐12′,9′′‐fluorene] and dispiro[fluorene‐9,6′‐indeno[2,1‐ a ]fluorene‐12′,9′′‐fluorene] is reported. Through a combined experimental and theoretical study, the different parameters that drive the regioselectivity of this cyclization reaction have been studied and are presented.

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