Self‐Assembly of Macrocyclic Boronic Esters Bearing Tellurophene Moieties and Their Guest‐Responsive Phosphorescence | Zendy

Takahashi Kohei | Zendy; Shimo Shunsuke | Zendy; Hupf Emanuel | Zendy; Ochiai Junichi | Zendy; Braun Christina A. | Zendy; Torres Delgado William | Zendy; Xu Letian | Zendy; He Gang | Zendy; Rivard Eric | Zendy; Iwasawa Nobuharu | Zendy

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Self‐Assembly of Macrocyclic Boronic Esters Bearing Tellurophene Moieties and Their Guest‐Responsive Phosphorescence

Author(s) -

Takahashi Kohei,

Shimo Shunsuke,

Hupf Emanuel,

Ochiai Junichi,

Braun Christina A.,

Torres Delgado William,

Xu Letian,

He Gang,

Rivard Eric,

Iwasawa Nobuharu

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201901319

Subject(s) - phosphorescence , chemistry , quenching (fluorescence) , photochemistry , combinatorial chemistry , stereochemistry , fluorescence , quantum mechanics , physics

Guest‐controlled diastereoselective self‐assembly of a diboryltellurophene and a chiral tetrol bearing an indacene backbone was achieved to give either hetero‐ or homochiral macrocyclic boronic esters, selectively. The heterochiral isomer (hetero‐[2+2] Te ) exhibited a higher inclusion ability for electron‐deficient aromatic guests, leading to effective quenching of phosphorescence from the diboryltellurophene moieties. The reported macrocycles collectively represent a promising arene sensing approach based on phosphorescence.

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