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A General One‐Pot Methodology for the Preparation of Mono‐ and Bimetallic Nanoparticles Supported on Carbon Nanotubes: Application in the Semi‐hydrogenation of Alkynes and Acetylene
Author(s) -
LomelíRosales Diego A.,
Delgado Jorge A.,
Díaz de los Bernardos Miriam,
PérezRodríguez Sara,
Gual Aitor,
Claver Carmen,
Godard Cyril
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201901041
Subject(s) - bimetallic strip , acetylene , carbon nanotube , materials science , nanoparticle , nanotechnology , carbon fibers , chemical engineering , organic chemistry , chemistry , metallurgy , metal , composite material , engineering , composite number
A facile and straightforward methodology for the preparation of monometallic (copper and palladium) and bimetallic nanocatalysts (NiCu and PdCu) stabilized by a N‐heterocyclic carbene ligand is reported. Both colloidal and supported nanoparticles (NPs) on carbon nanotubes (CNTs) were prepared in a one‐pot synthesis with outstanding control on their size, morphology and composition. These catalysts were evaluated in the selective hydrogenation of alkynes and alkynols. PdCu/CNTs revealed an efficient catalytic system providing high selectivity in the hydrogenation of terminal and internal alkynes. Moreover, this catalyst was tested in the semi‐hydrogenation of acetylene in industrially relevant acetylene/ethylene‐rich model gas feeds and showed excellent stability even after 40 h of reaction.