Developing Bicatalytic Cascade Reactions: Ruthenium‐catalyzed Hydrogen Generation From Methanol | Zendy

Agapova Anastasiya | Zendy; Junge Henrik | Zendy; Beller Matthias | Zendy

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Developing Bicatalytic Cascade Reactions: Ruthenium‐catalyzed Hydrogen Generation From Methanol

Author(s) -

Agapova Anastasiya,

Junge Henrik,

Beller Matthias

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201900966

Subject(s) - dehydrogenation , ruthenium , methanol , formic acid , catalysis , chemistry , hydrogen , cascade , aqueous solution , inorganic chemistry , photochemistry , organic chemistry , chromatography

A novel state‐of‐the‐art bicatalytic system for hydrogen generation from aqueous methanol at low temperature and base concentration is described. Applying two molecularly defined ruthenium complexes A and B3 for methanol dehydrogenation at the same time under the same conditions, a synergistic effect is observed. This behavior is explained by the increase of the dehydrogenation of formic acid, which is formed as an intermediate, by the second catalyst B3 .

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