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Facile Preparation of Snowflake‐Like MnO 2 @NiCo 2 O 4 Composites for Highly Efficient Electromagnetic Wave Absorption
Author(s) -
Wei Shuang,
Wang Xiaoxia,
Zheng Yiwei,
Chen Tao,
Zhou Congli,
Chen Shougang,
Liu Jingquan
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201900352
Subject(s) - snowflake , nanorod , materials science , reflection loss , composite material , dielectric , heterojunction , absorption (acoustics) , dielectric loss , composite number , electromagnetic radiation , impedance matching , nanotechnology , optoelectronics , electrical impedance , optics , electrical engineering , physics , meteorology , snow , engineering
Snowflake‐like MnO 2 @NiCo 2 O 4 composites were successfully fabricated by employing crossed snowflake‐like MnO 2 nanorods as cores and one‐dimensional (1D) NiCo 2 O 4 nanoneedles as shells. Impressively, the MnO 2 @NiCo 2 O 4 composites exhibited a highly efficient electromagnetic wave (EMW) absorbing capability, and the minimum reflection loss (RL) value reached −58.4 dB at 6.8 GHz for a thickness of 4.0 mm. The reasons for the improved EMW absorption capability of snowflake‐like MnO 2 @NiCo 2 O 4 composites were analyzed. The unique core–shell structure, good impedance matching, and high dielectric loss were all found to be important contributors. Moreover, the interfacial polarization mainly stemmed from the heterostructure, a microcurrent generated from the 1D MnO 2 nanorods and NiCo 2 O 4 nanoneedles under alternating electromagnetic fields, and the synergistic effect from the different components were all beneficial to improve the EMW absorption performance. These results demonstrated that snowflake‐like MnO 2 @NiCo 2 O 4 composites could be utilized as promising materials for practical EMW absorbing applications.