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Frontispiece: Role of Association in Chiral Catalysis: From Asymmetric Synthesis to Spin Selectivity
Author(s) -
Ageeva Aleksandra A.,
Khramtsova Ekaterina A.,
Magin Ilya M.,
Purtov Peter A.,
Miranda Miguel A.,
Leshina Tatyana V.
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201887063
Subject(s) - selectivity , diastereomer , catalysis , chemistry , enantioselective synthesis , spin (aerodynamics) , combinatorial chemistry , stereochemistry , physics , organic chemistry , thermodynamics
Spin selectivity , which results in the difference between the chemically induced dynamic nuclear polarisation enhancement coefficients of dyad diastereomers, is a phenomenon observed for chiral systems. This Minireview discusses the chemical nature of spin selectivity and the role of chiral associates in the chiral catalysis of an elementary radical reaction: electron transfer in chiral dyads. For more information, see the Minireview by Ageeva et al. on page 18587 ff.