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Frontispiece: Rhodium(III) Complex with a Bulky Cyclopentadienyl Ligand as a Catalyst for Regioselective Synthesis of Dihydroisoquinolones through C−H Activation of Arylhydroxamic Acids
Author(s) -
Trifonova Evgeniya A.,
Ankudinov Nikita M.,
Kozlov Maxim V.,
Sharipov Mikhail Y.,
Nelyubina Yulia V.,
Perekalin Dmitry S.
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201886264
Subject(s) - rhodium , regioselectivity , cyclopentadienyl complex , alkene , catalysis , chemistry , ligand (biochemistry) , stereochemistry , polymer chemistry , organic chemistry , receptor , biochemistry
A page of a coloring book shows the molecules of hydroxamic acid and alkene at the fork of the road. The signpost with a traditional weathervane figure—the cyclopentadienyl rhodium catalyst—directs the reaction to the right to give the 4‐substituted dihydroisoquinolones. For more information, see the Full Paper by D. S. Perekalin et al. on page 16570 ff.