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Frontispiece: Tuning of High Spin Ground State and Slow Magnetic Relaxation within Trimetallic Cyanide‐Bridged {Ni II x Co II 9− x [W V (CN) 8 ] 6 } and {Mn II x Co II 9− x [W V (CN) 8 ] 6 } Clusters
Author(s) -
Chorazy Szymon,
Majcher Anna M.,
Kozieł Marcin,
Kobylarczyk Jedrzej,
Ohkoshi Shinichi,
Podgajny Robert
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201885865
Subject(s) - cyanide , fortress (chess) , crystallography , ground state , chemistry , relaxation (psychology) , spin (aerodynamics) , physics , atomic physics , inorganic chemistry , history , ancient history , social psychology , psychology , thermodynamics
The battle to conquer the magnificent molecular fortress located at the breath‐taking view of primeval desert mountain terrain is depicted in the graphic. Some positions are still to be taken, and they witness the dreadful duel scenes between the soldiers of the opposite armies that claim their rights. As their forces and skills are well balanced, the fortress could easily become a mixed dominion! Such image illustrates the formation of polynuclear trimetallic cyanide‐bridged clusters within the 15‐nuclear molecular platform, resulting in the composition dependent magnetic properties. For more information see the Full Paper by R. Podgajny et al. on page 15533 ff.