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Frontispiece: Alkylating Reagents Employed in Catellani‐Type Reactions
Author(s) -
Liu ZeShui,
Gao Qianwen,
Cheng HongGang,
Zhou Qianghui
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201885864
Subject(s) - reagent , norbornene , palladium , aryl , combinatorial chemistry , catalysis , chemistry , organic chemistry , polymer , alkyl , monomer
Alkylating reagents for use in the Catellani reaction are discussed. This reaction utilizes the synergistic interplay of palladium and norbornene catalysis to facilitate sequential ortho ‐C−H functionalization and ipso termination of aryl iodides in a single operation. It is a powerful transformation for the preparation of highly substituted arenes, but with huge unrevealed potential. For more details, see the Minireview by H.‐G. Cheng, Q. Zhou et al. on page 15461 ff.
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