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Frontispiece: Hydroxylamine Derivatives as Nitrogen‐Radical Precursors in Visible‐Light Photochemistry
Author(s) -
Davies Jacob,
Morcillo Sara P.,
Douglas James J.,
Leonori Daniele
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201884765
Subject(s) - hydroxylamine , photocatalysis , radical , photochemistry , visible spectrum , ionic bonding , chemistry , nitrogen , molecule , organic chemistry , materials science , catalysis , ion , optoelectronics
Forming C−N bonds is fundamental to the preparation of molecules with wide applications. Nitrogen radicals offer alternative reaction pathways that are complementary to both ionic and transition‐metal‐based reactivities. In recent year, visible‐light photocatalysis has enabled the development of many approaches for the generation and use of this highly reactive species from simple and easy to make hydroxylamine precursors. For more information see the Concept aarticle by D. Leonori et al. on page 12154 ff.