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Frontispiece: Majority‐Rules Effect and Allostery in Molecular Recognition of Calix[4]arene‐Based Triple‐Stranded Metallohelicates
Author(s) -
Yamasaki Yutaro,
Shio Hidemi,
Amimoto Tomoko,
Sekiya Ryo,
Haino Takeharu
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201883465
Subject(s) - chirality (physics) , stereochemistry , molecular recognition , helicity , chemistry , allosteric regulation , crystallography , triple helix , physics , molecule , biochemistry , organic chemistry , receptor , chiral symmetry , quantum mechanics , nambu–jona lasinio model , quark
Triple‐stranded metallohelicates possessing the internal guest binding cavities surrounded by the calix[4]arene units are depicted in the graphic. The chirality of a guest is transferred to the helicity of the helicates. The majority‐rules effects in the chiral guest binding are found in the helicates possessing the conformationally‐coupled guest binding sites. For more information see the Full Paper by T. Haino et al. on page 8558 ff.