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Front Cover: Selective Encapsulation and Separation of Dihalobenzene Isomers with Discrete Heterometallic Macrocages (Chem. Eur. J. 71/2018)
Author(s) -
Zhang HaiNing,
Lu Ye,
Gao WenXi,
Lin YueJian,
Jin GuoXin
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201805958
Subject(s) - rhodium , front cover , encapsulation (networking) , benzene , chemistry , combinatorial chemistry , medicinal chemistry , organic chemistry , computer science , catalysis , cover (algebra) , engineering , mechanical engineering , computer network
A series of discrete Cp*Rh‐based metallosupramolecular architectures was constructed, featuring stable heteroarylrhodium(III) units ranging from metallarectangles to heterometallic macrocages and hexanuclear prisms, prepared by heterocyclic boronic acids and rhodium precursors under mild conditions. The excellent host–guest abilities of these macrocages were utilized to enable selective, reversible encapsulation of para ‐dihaloaromatic benzene derivatives and their separation from their constitutional isomers. More information can be found in the Full Paper by G.‐X. Jin et al. on page 18913.