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Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N‐Heterocyclic Carbene/Palladium Catalysis
Author(s) -
Haruki Hiroki,
Yasuda Shigeo,
Nagao Kazunori,
Ohmiya Hirohisa
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201805955
Subject(s) - allylic rearrangement , carbene , palladium , catalysis , chemistry , organic chemistry , medicinal chemistry , combinatorial chemistry
Dehydrative allylation between widely available aldehydes and allylic alcohols to afford β,γ‐unsaturated ketones was enabled by a synergistic merger of a thiazolium N‐heterocyclic carbene catalyst and a palladium‐bisphosphine catalyst.