A Switch in the Hydrophobic/Hydrophilic Gas‐Adsorption Character of Prussian Blue Analogues: An Affinity Control for Smart Gas Sorption | Zendy

Boudjema Lotfi | Zendy; Long Jérôme | Zendy; Salles Fabrice | Zendy; Larionova Joulia | Zendy; Guari Yannick | Zendy; Trens Philippe | Zendy

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A Switch in the Hydrophobic/Hydrophilic Gas‐Adsorption Character of Prussian Blue Analogues: An Affinity Control for Smart Gas Sorption

Author(s) -

Boudjema Lotfi,

Long Jérôme,

Salles Fabrice,

Larionova Joulia,

Guari Yannick,

Trens Philippe

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201804730

Subject(s) - prussian blue , adsorption , sorption , polymer , chemical engineering , molecule , character (mathematics) , materials science , hexane , porosity , metal , chemistry , inorganic chemistry , organic chemistry , geometry , mathematics , electrode , engineering , electrochemistry

Porous coordination polymers are molecule‐based materials presenting a high degree of tunability, which offer many advantages for targeted applications over conventional inorganic materials. This work demonstrates that the hydrophilic/hydrophobic character of Prussian blue analogues having a lipophilic feature may be tuned to optimize the gas adsorption properties. The role of the coordinatively unsaturated metal sites is emphasized through a combination of theoretical and experimental study of water, ethanol, and n ‐hexane adsorption.

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