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Cover Feature: Diferrate [Fe 2 (CO) 6 (μ‐CO){μ‐P(aryl) 2 }] − as Self‐Assembling Iron/Phosphor‐Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction—Spectroscopic Insights (Chem. Eur. J. 60/2018)
Author(s) -
Fischer Steffen,
Rösel Arend,
Kammer Anja,
Barsch Enrico,
Schoch Roland,
Junge Henrik,
Bauer Matthias,
Beller Matthias,
Ludwig Ralf
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201804531
Subject(s) - catalysis , hydrogen production , photocatalysis , sulfur , phosphor , chemistry , hydrogen , cover (algebra) , water splitting , catalytic cycle , materials science , photochemistry , organic chemistry , mechanical engineering , optoelectronics , engineering
Understanding the mechanism of photocatalytic water reduction is essential for the development of effective catalysts. A new, self‐assembling, and sulfur‐free [FeFe]‐hydrogenase mimic, which shows good catalytic activity, is described. The action of the visible‐light‐driven iron catalyst within the cycle of H 2 production from water is monitored by a combination of in‐situ spectroscopic methods. More information can be found in the Full Paper by R. Ludwig et al. on page 16052.