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Cover Feature: Incorporation of a p ‐Phenylene Unit into the Azuliporphyrinogens Frame—Oxidation and Ruthenium Cluster Coordination (Chem. Eur. J. 55/2018)
Author(s) -
Sprutta Natasza,
Hassa Agnieszka,
Białek Michał J.,
KodźWichowska Karolina,
Kupietz Kamil,
LatosGrażyński Lechosław
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201804477
Subject(s) - ruthenium , cover (algebra) , cluster (spacecraft) , tetrahedron , phenylene , unit (ring theory) , chemistry , crystallography , stereochemistry , materials science , computer science , engineering , mathematics , organic chemistry , catalysis , polymer , mechanical engineering , mathematics education , programming language
Diazuli‐ p ‐benzithiaporphyrinogens and their oxidized polycarbocationic forms provide intriguing examples of azuliporphyrinoids that incorporate the p ‐phenylene unit into the macrocyclic framework of expanded porphyrinoid. In their manuscript, L. Latos‐Grażyński and co‐workers also demonstrated that these hybrid macrocycles can acquire a role of a conformationally flexible carbon platforms, that possess well established π‐coordination properties toward tetrahedral Ru 4 (CO) 9 clusters, confined in the original macrocyclic architecture. More information can be found in the Full Paper by N. Sprutta, L. Latos‐Grażyński et al. on page 14686.