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Tailored Palladate Tunable Aryl Alkyl Ionic Liquids (TAAILs)
Author(s) -
Schroeter Felix,
Soellner Johannes,
Strassner Thomas
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201804431
Subject(s) - ionic liquid , aryl , alkyl , melting point , ion , ionic bonding , chemistry , materials science , inorganic chemistry , organic chemistry , catalysis
We present a new class of tunable aryl alkyl ionic liquids (TAAILs) containing different palladate counter ions. Solid‐state structures for representative compounds have been obtained. Their properties are presented in comparison to those of newly synthesized and reported palladate ionic liquids with conventional counter ions. It was found that the aryl substitution pattern and the type of anion have a profound influence on the melting point. The speciation of the different anions in solution has been rationalized by DFT calculations.