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Dysprosium Single‐Molecule Magnets with Bulky Schiff Base Ligands: Modification of the Slow Relaxation of the Magnetization by Substituent Change
Author(s) -
Long Jérôme,
Basalov Ivan V.,
Forosenko Natalia V.,
Lyssenko Konstantin A.,
Mamontova Ekaterina,
Cherkasov Anton V.,
Damjanović Marko,
Chibotaru Liviu F.,
Guari Yannick,
Larionova Joulia,
Trifonov Alexander A.
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201804429
Subject(s) - dysprosium , schiff base , bifunctional , single molecule magnet , magnetization , substituent , molecule , magnet , photoluminescence , relaxation (psychology) , materials science , crystallography , chemistry , inorganic chemistry , stereochemistry , optoelectronics , organic chemistry , magnetic field , physics , catalysis , social psychology , psychology , quantum mechanics
The synthesis, and magnetic and photoluminescence investigations of two bifunctional dysprosium complexes based on tridentate Schiff base ligands is reported. Magnetic investigations reveal a genuine single‐molecule magnet (SMM) behavior, with out‐of‐phase signals up to 60 K, and tunable emission arising from the Schiff base ligands.