Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate | Zendy

Benito Quentin | Zendy; Balogh Cristina M. | Zendy; El Moll Hani | Zendy; Gacoin Thierry | Zendy; Cordier Marie | Zendy; Rakhmatullin Aydar | Zendy; Latouche Camille | Zendy; MartineauCorcos Charlotte | Zendy; Perruchas Sandrine | Zendy

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Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate

Author(s) -

Benito Quentin,

Balogh Cristina M.,

El Moll Hani,

Gacoin Thierry,

Cordier Marie,

Rakhmatullin Aydar,

Latouche Camille,

MartineauCorcos Charlotte,

Perruchas Sandrine

Publication year - 2018

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201804377

Subject(s) - luminescence , phosphine , solvatochromism , iodide , copper , solvent exposure , solvent , chemistry , photochemistry , inorganic chemistry , materials science , organic chemistry , optoelectronics , catalysis

A copper iodide complex coordinated by three phosphine ligands with the formula [Cu 2 I 2 (Ph 2 PC 2 (C 6 H 4 )C 2 PPh 2 ) 3 ] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent‐dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.

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