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Integration of an N‐Heterocyclic Carbene Precursor into a Covalent Triazine Framework for Organocatalysis
Author(s) -
Troschke Erik,
Nguyen Khoa Dang,
Paasch Silvia,
Schmidt Johannes,
Nickerl Georg,
Senkovska Irena,
Brunner Eike,
Kaskel Stefan
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201804373
Subject(s) - moiety , umpolung , carbene , organocatalysis , triazine , chemistry , covalent bond , combinatorial chemistry , catalysis , polymer chemistry , organic chemistry , nucleophile , enantioselective synthesis
The successful incorporation of a thermally fragile imidazolium moiety into a covalent triazine framework resulted in a heterogeneous organocatalyst active in carbene‐catalyzed umpolung reaction. The structural integrity of the imidazolium moiety was confirmed by combining solid‐state NMR and XPS experiments.