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Efficient Degradation of Phenol and 4‐Nitrophenol by Surface Oxygen Vacancies and Plasmonic Silver Co‐Modified Bi 2 MoO 6 Photocatalysts
Author(s) -
Shen Huidong,
Xue Wenwen,
Fu Feng,
Sun Jiefang,
Zhen Yanzhong,
Wang Danjun,
Shao Bing,
Tang Junwang
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201804267
Subject(s) - photocatalysis , photodegradation , surface plasmon resonance , materials science , oxygen , photochemistry , phenol , calcination , nanoparticle , 4 nitrophenol , raman spectroscopy , visible spectrum , electron paramagnetic resonance , metal , chemical engineering , chemistry , nanotechnology , catalysis , organic chemistry , optoelectronics , optics , physics , engineering , metallurgy , nuclear magnetic resonance
In this work, the surface plasmon resonance effect of metallic Ag, surface oxygen vacancies (SOVs), and Bi 2 MoO 6 (BMO) material were rationally combined to construct new oxygen‐vacancy‐rich Ag/Bi 2 MoO 6 (A/BMO‐SOVs) photocatalysts. Their synergistic effect on the photocatalytic degradation of phenol and 4‐nitrophenol under visible‐light irradiation ( λ ≥420 nm) was also investigated. TEM, EPR, and Raman spectra demonstrate the co‐existence of metallic Ag nanoparticles, surface oxygen vacancies, and Bi 2 MoO 6 due to a controlled calcination process. The experimental results disclose that the 2 %A/BMO‐SOVs‐375 sample exhibited the highest photocatalytic activity for the degradation of both phenol and 4‐nitrophenol under visible‐light irradiation, achieving nearly 100 and 80 % removal efficiency, respectively, and demonstrated the apparent reaction rate constants ( k app ) 183 and 26.5 times, respectively, higher than that of pure Bi 2 MoO 6 . The remarkable photodegradation performance of A/BMO‐SOVs for organic substances is attributed to the synergistic effect between the surface oxygen vacancies, metallic Ag nanoparticles, and Bi 2 MoO 6 , which not only improves the visible‐light response ability, but also facilitates charge separation. Thus, this work provides an effective strategy for the design and fabrication of highly efficient photocatalysts through integrating surface oxygen vacancies and the surface plasmon resonance effect of nanoparticles, which has the potential for both water treatment and air purification.