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Iron‐Incorporated α‐Ni(OH) 2 Hierarchical Nanosheet Arrays for Electrocatalytic Urea Oxidation
Author(s) -
Xie Junfeng,
Liu Weiwei,
Lei Fengcai,
Zhang Xiaodong,
Qu Haichao,
Gao Li,
Hao Pin,
Tang Bo,
Xie Yi
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201803718
Subject(s) - nanosheet , urea , electrochemistry , materials science , electrocatalyst , inorganic chemistry , prussian blue , chemistry , chemical engineering , nanotechnology , electrode , biochemistry , engineering
An iron‐incorporated α‐Ni(OH) 2 nanosheet array catalyst characterized by hierarchical surface nanobelts and robust urea oxidation performance are reported. The unique single‐crystalline belt‐on‐sheet hierarchical nanostructure was identified and it endows more reactive edges for the Ni 2+ ‐to‐Ni 3+ pre‐oxidation process to boost the generation of active high‐valence species for the urea oxidation reaction (UOR). Benefitting from the optimal Fe concentration, the UOR activity was further optimized owing to the favorable reaction kinetics. With the synergistic benefits of the increased surface areas, improved charge transfer behavior, favorable reaction kinetics and excellent structural stability, the iron‐incorporated α‐Ni(OH) 2 hierarchical nanosheet array catalyst displays significantly improved UOR performance with both high activity and outstanding operational stability. This work could guide the design of advanced UOR catalysts for wastewater treatment and clean energy production in the future.