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Cover Feature: New Vistas in Transmetalation with Discrete “AgCF 3 ” Species: Implications in Pd‐Mediated Trifluoromethylation Reactions (Chem. Eur. J. 46/2018)
Author(s) -
Martínez de Salinas Sara,
Mudarra Ángel L.,
BenetBuchholz Jordi,
Parella Teodor,
Maseras Feliu,
PérezTemprano Mónica H.
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201803632
Subject(s) - transmetalation , cover (algebra) , trifluoromethylation , feature (linguistics) , palladium , chemistry , computer science , catalysis , combinatorial chemistry , engineering , organic chemistry , philosophy , mechanical engineering , linguistics , alkyl , trifluoromethyl
Organosilver(I) species have previously demonstrated their potential as coupling partners in Pd‐catalyzed transformations, but this ability is far from being fully exploited. Discrete “AgCF 3 ” complexes with a new silver ate complex, (Cs)[Ag(CF 3 ) 2 ], have been employed in the highlighted paper. Their unique structure can tackle some usually overshadowed limitations related to the transmetalation step within the trifluoromethylation area. More information can be found in the Communication by M. H. Pérez‐Temprano, et al. on page 11895.