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Cover Feature: Mechanism of Mechanochemical C−H Bond Activation in an Azobenzene Substrate by Pd II Catalysts (Chem. Eur. J. 42/2018)
Author(s) -
Bjelopetrović Alen,
Lukin Stipe,
Halasz Ivan,
Užarević Krunoslav,
Đilović Ivica,
Barišić Dajana,
Budimir Ana,
Juribašić Kulcsár Marina,
Ćurić Manda
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201803520
Subject(s) - azobenzene , catalysis , reactivity (psychology) , kinetics , substrate (aquarium) , chemistry , reaction mechanism , crystallography , medicinal chemistry , photochemistry , stereochemistry , polymer chemistry , molecule , organic chemistry , physics , medicine , alternative medicine , oceanography , pathology , quantum mechanics , geology
A comparative mechanistic study of the mechanochemical C−H bond activation in an unsymmetrical azobenzene by common Pd(II) catalysts is reported, using liquid and/or solid additives. The C−H bond activation was achieved by all used Pd(II) precursors and their reactivity increases in the order [Pd(OAc) 2 ] 3