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Influence of Temperature and Electrolyte Concentration on the Structure and Catalytic Oxygen Evolution Activity of Nickel–Iron Layered Double Hydroxide
Author(s) -
Andronescu Corina,
Seisel Sabine,
Wilde Patrick,
Barwe Stefan,
Masa Justus,
Chen YenTing,
Ventosa Edgar,
Schuhmann Wolfgang
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201803165
Subject(s) - hydroxide , catalysis , electrolyte , oxygen evolution , amorphous solid , electrolysis , electrochemistry , raman spectroscopy , nickel , inorganic chemistry , materials science , chemical engineering , oxygen , polarization (electrochemistry) , chemistry , metallurgy , electrode , crystallography , physics , organic chemistry , optics , engineering , biochemistry
NiFe layered double hydroxide (LDH) is inarguably the most active contemporary catalyst for the oxygen evolution reaction under alkaline conditions. However, the ability to sustain unattenuated performance under challenging industrial conditions entailing high corrosivity of the electrolyte (≈30 wt. % KOH), high temperature (>80 °C) and high current densities (>500 mA cm −2 ) is the ultimate criterion for practical viability. This work evaluates the chemical and structural stability of NiFe LDH at conditions akin to practical electrolysis, in 30 % KOH at 80 °C, however, without electrochemical polarization, and the resulting impact on the OER performance of the catalyst. Post‐analysis of the catalyst by means of XRD, TEM, FT‐IR, and Raman spectroscopy after its immersion into 7.5 m KOH at 80 °C for 60 h revealed a transformation of the structure from NiFe LDH to a mixture of crystalline β‐Ni(OH) 2 and discrete predominantly amorphous FeOOH containing minor non‐homogeneously distributed crystalline domains. These structural and compositional changes led to a drastic loss of the OER activity. It is therefore recommended to study catalyst stability at industrially relevant conditions.