Beyond Common Metal–Metal Bonds, κ 3 ‐Bis(donor)ferrocenyl→Transition‐Metal Interactions | Zendy

Ringenberg Mark R. | Zendy

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Beyond Common Metal–Metal Bonds, κ 3 ‐Bis(donor)ferrocenyl→Transition‐Metal Interactions

Author(s) -

Ringenberg Mark R.

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201803150

Subject(s) - transition metal , ferrocene , metal , crystallography , chemistry , chelation , computational chemistry , materials science , stereochemistry , inorganic chemistry , organic chemistry , electrochemistry , catalysis , electrode

Ligands with 1,1′‐bis(donor)ferrocene motif are capable of a wide range of binding modes, including the trans chelation mode in which there is a Fe−M interaction (κ 3 ‐D,Fe,D), in the form of a dative Fe→TM bond (TM=transition metal). This Minireview will explore the nature of this Fe–TM interaction thorough select examples as well as how to characterize a Fe→TM dative bond using physical, computational, and spectroscopic techniques.

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