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Realizing the Potential of Acetylenedicarboxylate by Functionalization to Halofumarate in Zr IV Metal–Organic Frameworks
Author(s) -
Ma Ntep Tobie J. Matemb,
Reinsch Helge,
Moll Bastian,
Hastürk Emrah,
Gökpinar Serkan,
Breitzke Hergen,
Schlüsener Carsten,
Schmolke Laura,
Buntkowsky Gerd,
Janiak Christoph
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201802838
Subject(s) - surface modification , metal , metal organic framework , chemistry , organic chemistry , adsorption
A strategy was developed to obtain from acetylenedicarboxylic acid either an acetylenedicarboxylate‐based Zr IV metal–organic framework (MOF) with fcu topology or a halo‐functionalized‐MOF‐801 through in situ ligand hydrohalogenation. The new materials feature exceptionally high hydrophilicity and CO 2 /H 2 adsorption energetics. The acetylenedicarboxylate linker and its functionalizable triple‐bond discloses its potential in the engineering of microporous materials with targeted properties.