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Mono‐ and Bisionic Mo‐ and W‐Based Schrock Catalysts for Biphasic Olefin Metathesis Reactions in Ionic Liquids
Author(s) -
Schowner Roman,
Elser Iris,
Toth Florian,
Robe Emmanuel,
Frey Wolfgang,
Buchmeiser Michael R.
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201802472
Subject(s) - chlorobenzene , catalysis , ionic liquid , pyridinium , phosphonium , chemistry , toluene , salt metathesis reaction , heptane , olefin fiber , metathesis , olefin metathesis , ionic bonding , organic chemistry , polymerization , ion , polymer
An extensive series of the first ionic Mo‐ and W‐based Schrock‐type catalysts based on pyridinium and phosphonium tagged aryloxide ligands were prepared. Bisionic complexes of the general formula Mo(Imido)(CHR)(OR′) 2 (OTf) 2 and monoionic monoaryloxide pyrrolide (pyr) (MAP‐type) catalysts [M(Imido)(CHR)(OR′)(pyr) + ][A − ] were successfully employed and tested in various olefin metathesis benchmark reactions under both, homogeneous and biphasic conditions using pyrrole and, for the first time with Schrock‐type catalysts, ionic liquids as the polar phase. Productivities under biphasic conditions up to several thousand turn overs were achieved and are comparable to those obtained in reactions carried out in chlorobenzene or toluene. Metal contamination in the nonpolar product‐containing heptane phase was <2 ppm.