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Mixed‐Phase 2D‐MoS 2 as an Effective Photocatalyst for Selective Aerobic Oxidative Coupling of Amines under Visible‐Light Irradiation
Author(s) -
Girish Yarabhally R.,
Biswas Rohin,
De Mrinmoy
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201802468
Subject(s) - photocatalysis , heterojunction , materials science , semiconductor , phase (matter) , oxidative coupling of methane , irradiation , photochemistry , electron transfer , metal , chemical engineering , optoelectronics , chemistry , catalysis , organic chemistry , physics , nuclear physics , engineering , metallurgy
Metal‐semiconductor heterojunctions play a vital role in photocatalysis, yet their preparation can be exceedingly difficult. The heterojunction helps not only to separate the charges and inhibit recombination processes but also to transfer the photogenerated electron/hole to the reacting molecule. Here, we demonstrate 1T (metallic)‐2H (semiconducting) phase boundaries intrinsic to individual sheets of chemically exfoliated 2D‐MoS 2 can serve as heterojunctions for enhanced photocatalysis in comparison to only semiconducting phase. Due to the abundance of heterojunctions in these multiphasic materials, chemically exfoliated 2D‐MoS 2 provides improved stability and transfer of photogenerated charges to the reactants, giving better yield. We demonstrate that this easy to synthesize material is an effective photocatalyst for the aerobic oxidative coupling of amines to imines under visible light irradiation. Given its broad applications, we believe mixed phase 2D‐MoS 2 can be of interest to several industrial synthetic applications related to semiconductor‐based photocatalysis. As an added advantage, this heterogeneous photocatalyst can be recycled for several times up to five cycles without any significant loss in the activity.