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From LiB 3 O 5 to NaRbB 6 O 9 F 2 : Fluorine‐Directed Evolution of Structural Chemistry
Author(s) -
Han Shujuan,
Zhang Bingbing,
Yang Zhihua,
Pan Shilie
Publication year - 2018
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201802466
Subject(s) - fluorine , chemistry , mineralogy , crystallography , materials science , organic chemistry
Introducing fluorine into borates indicates the direction for structural evolution. A new fluorooxoborate, NaRbB 6 O 9 F 2 featuring a unique [B 6 O 9 F 2 ] ∞ layered structure and excellent optical properties has been synthesized. It is further demonstrated that incorporation of fluorine can enrich the structural chemistry of borates.